Get Applications of Domino Transformations in Organic Synthesis, PDF

By Scott A. Snyder, Erick M. Carreira, Carl P. Decicco, Alois Fürstner, Guido Koch, Gary A. Molander, Ernst Schaumann

ISBN-10: 3131731419

ISBN-13: 9783131731418

ISBN-10: 3132028517

ISBN-13: 9783132028517

The swift speed of evolution in domino, or cascade-based variations has revolutionized the perform of chemical synthesis for the production of common items, designed molecules, and pharmaceuticals.


"Science of Synthesis: purposes of Domino changes in natural Synthesis" explores the subject completely and systematically, serving because the foundation for sensible functions and destiny examine. The 2-volume set offers the state of the art when it comes to layout, technique, and experimental techniques, resulting in a number of occasions being finished inside a unmarried response vessel. The content material is geared up through the middle kind of response used to start up the development, be it a pericyclic response, a metal-mediated transformation, radical chemistry, or an acid-induced cascade between many others.


Volume 1 covers polyene/cation-pi cyclizations, metathesis, radical, and metal-mediated reactions, and non-radical skeletal rearrangements.

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Extra resources for Applications of Domino Transformations in Organic Synthesis, Volume 1

Sample text

6 Intermolecular Trapping/Trapping Pathways . . . . . . . . . . . . . . . . 7 Conclusions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1 Protic Acid/Base Induced Reactions D. Adu-Ampratwum and C. J. 1 Protic Acid/Base Induced Reactions . . . . . . . . . . . . . . . . . . . 1 Intramolecular Epoxide-Opening Cyclizations . . . . . . . . . . . . . . . 1 Protic Acid Induced Intramolecular Epoxide Openings .

1 Acetate Migration and Reaction with Alkynes . . . . . . . . . . . . . . . 2 Acetate Migration and Reaction with Alkenes . . . . . . . . . . . . . . . 6 Acetate Migration and Ring-Opening Reactions . . . . . . . . . . . . . . 1 Cyclopentannulations . . . . . . . . . . . . . . . . . . . . . . . . . . . 2 Cyclohexannulations . . . . . . . . . . . . . . . . . . . . . . . . . . . 3 Cycloheptannulations .

2 Asymmetric Total Synthesis of Racemic Merrilactone A . . . . . . . . . . . 3 Allenic Pauson–Khand Reaction . . . . . . . . . . . . . . . . . . . . . . 1 Total Synthesis of (+)-Achalensolide . . . . . . . . . . . . . . . . . . . . 2 Synthesis of 6,12-Guaianolide . . . . . . . . . . . . . . . . . . . . . . . 3 Stereoselective Total Syntheses of Uncommon Sesquiterpenoids . . . . . . 4 14-Step Synthesis of (+)-Ingenol from (+)-3-Carene .

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Applications of Domino Transformations in Organic Synthesis, Volume 1 by Scott A. Snyder, Erick M. Carreira, Carl P. Decicco, Alois Fürstner, Guido Koch, Gary A. Molander, Ernst Schaumann


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