Download e-book for iPad: Carbohydrate Chemistry: v. 10 by J.S. Brimacombe

By J.S. Brimacombe

ISBN-10: 0851860923

ISBN-13: 9780851860923

Carbohydrate Chemistry offers evaluate assurance of all courses proper to the chemistry of monosaccharides and oligosaccharides in a given yr. the quantity of analysis during this box showing within the natural chemical literature is expanding due to the more desirable significance of the topic, specially in parts of medicinal chemistry and biology. In no a part of the sphere is that this extra obvious than within the synthesis of oligosaccharides required by way of scientists operating in glycobiology. Clycomedicinal chemistry and its reliance on carbohydrate synthesis is now rather well validated, for instance, through the coaching of particular carbohydrate- established antigens, particularly cancer-specific oligosaccharides and glycoconjugates. insurance of themes equivalent to nucleosides, amino-sugars, alditols and cyclitols additionally covers a lot examine of relevance to organic and medicinal chemistry. each one quantity of the sequence brings jointly references to all released paintings in given components of the topic and serves as a complete database for the lively examine chemist. professional Periodical experiences offer systematic and distinctive assessment assurance in significant components of chemical study. Compiled via groups of major experts within the suitable topic parts, the sequence creates a special carrier for the lively study chemist, with ordinary, in-depth money owed of growth particularly fields of chemistry. topic assurance inside diverse volumes of a given name is the same and booklet is on an annual or biennial foundation.

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D. Audichya, T. R. Ingle, and J. L. Bose, Indian J. , 1976, 14B, 369 (Chem. , 1976, 85, 193 024x). L. Rosenfeld and Y . C. , 1976, 46, 155. K. Kawaguchi and N. Kashimura, Agric. and Biol. Chem. (Japan), 1976, 40, 241. E. E. Lee, G. Keaveney, A. Hartigan, and P. S . , 1976, 49, 475. -glycoside, whereas the chloroethyl derivatives (1 7), (18), and (19) yielded FH,OAc ‘ \ O--C-OCH,R I M C (16) R = Me (17) R = CH,CI (18) R = CHCl, (19) R = CCI, mixtures containing 16, 50, and 67%, respectively, of the corresponding a-glycoside.

Mine, and T . , 1976,48, 197. lS3 4,6-Dichloro-4,6-dideoxy-~-gaIactose reacted with cyclohexanone ethylene acetal in the presence of an acid catalyst to give the acyclic derivative (48), which was converted into the corresponding 5 - u l 0 s e . ~ Treatment ~~ with base converted (48) into the 5,6-anhydro-derivative, which was hydrolysed to give the L-idose diacetal(49), presumably by way of a 4,5-anhydro-~-glucosederivative. -The formation and hydrolysis of O-tetrahydrofuran2-yl derivatives have been mentioned in Chapter 4.

1976, 50, 1883. 2 0 8 K. , 1976, 48, 290. e o D T. M. Fyles and C . C . Leznoff, Cannd. J. , 1976, 54, 935. 210 S. Valentekovid and D. , 1976, 47, 35. 211 D. Keglevid, J. Horvat, and F. , 1976, 47, 49. 212 Y. Ishido, N. Nakazaki, and N. S. Chem. , 1976, 832. A. Holy, J . Carbohydrates, Nucleosides, Nucleotides, 1975, 2, 25 1. 214 J. Stawinski, T. Hozumi, and S. A. S. Chem. , 1976, 243. g. 'l Metalation of 2,3,4,6-tetra-0-benzyl-~-g~ucopyranose using n-butyl-lithium in T H F at ca. 21s This sequence therefore provides a single pathway to 1-0-acyl-a- and -p-u-glucopyranoses.

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Carbohydrate Chemistry: v. 10 by J.S. Brimacombe


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